Check out example codes for "view t-sql mail configuration". It will help you in understanding the concepts better.

Code Example 1

EXEC msdb.dbo.sysmail_help_configure_sp;
EXEC msdb.dbo.sysmail_help_account_sp;
EXEC msdb.dbo.sysmail_help_profile_sp;
EXEC msdb.dbo.sysmail_help_profileaccount_sp;
EXEC msdb.dbo.sysmail_help_principalprofile_sp;

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